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Proceedings of the 4th Sriwijaya International Conference on Basic and Applied Sciences, SICBAS 2025, 6 November 2025, Palembang, Indonesia

Research Article

Utilization of Petroleum Sludge Waste as an Al-Fe Oxide/C Adsorbent and Its Characterization

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  • @INPROCEEDINGS{10.4108/eai.6-11-2025.2364332,
        author={Zainal  Fanani and Alya  Selviani and Arum  Setiawan and Julinar  Julinar},
        title={Utilization of Petroleum Sludge Waste as an Al-Fe Oxide/C Adsorbent and Its Characterization},
        proceedings={Proceedings of the 4th Sriwijaya International Conference on Basic and Applied Sciences, SICBAS 2025, 6 November 2025, Palembang, Indonesia},
        publisher={EAI},
        proceedings_a={SICBAS},
        year={2026},
        month={8},
        keywords={Oil sludge Al-Fe oxide/C adsorbent methylene blue eriochrome black T hydrothermal synthesis},
        doi={10.4108/eai.6-11-2025.2364332}
    }
    
  • Zainal Fanani
    Alya Selviani
    Arum Setiawan
    Julinar Julinar
    Year: 2026
    Utilization of Petroleum Sludge Waste as an Al-Fe Oxide/C Adsorbent and Its Characterization
    SICBAS
    EAI
    DOI: 10.4108/eai.6-11-2025.2364332
Zainal Fanani1,*, Alya Selviani1, Arum Setiawan2, Julinar Julinar1
  • 1: Department of Chemistry, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Indonesia
  • 2: Department of Biology, Faculty of Mathematics and Natural Sciences, Universitas Sriwijaya, Indonesia
*Contact email: zainalf314@gmail.com

Abstract

This research addresses the conversion of hazardous petroleum oil sludge (POS) into an Al-Fe Oxide/C adsorbent via sulfuric acid (H₂SO₄) activation and hydrothermal treatment. Leveraging the inherent C (51.7%), Al (1.6%), and Fe (10.8%) content in the waste, the study aims to synthesize an effective adsorbent for methylene blue (MB) and eriochrome black T (EBT) removal. Characterization using SEM-EDX and FTIR confirmed the formation of active acid sites. The results showed total acidity of 5.6338 mmol/g. Adsorption performance was optimized based on pH and contact time, following the Langmuir-Freundlich isotherm model. This study demonstrates a sustainable approach to B3 waste management by producing a high-value adsorbent for industrial wastewater treatment.

Keywords
Oil sludge, Al-Fe oxide/C, adsorbent, methylene blue, eriochrome black T, hydrothermal synthesis
Published
2026-08-12
Publisher
EAI
http://dx.doi.org/10.4108/eai.6-11-2025.2364332
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