Research Article
Pretreatment and Adsorption Effects on Stability and Morphology Structure of TCNQ-Based Porous Coordination
@INPROCEEDINGS{10.4108/eai.18-10-2018.2287329, author={Moondra Zubir and Marini Damanik and Hafni Indriati Nasution and Minda Shafina Syafei}, title={Pretreatment and Adsorption Effects on Stability and Morphology Structure of TCNQ-Based Porous Coordination }, proceedings={Proceedings of The 5th Annual International Seminar on Trends in Science and Science Education, AISTSSE 2018, 18-19 October 2018, Medan, Indonesia}, publisher={EAI}, proceedings_a={AISTSSE}, year={2019}, month={10}, keywords={magnetic fields crystal structure morphology adsorption}, doi={10.4108/eai.18-10-2018.2287329} }- Moondra Zubir
Marini Damanik
Hafni Indriati Nasution
Minda Shafina Syafei
Year: 2019
Pretreatment and Adsorption Effects on Stability and Morphology Structure of TCNQ-Based Porous Coordination
AISTSSE
EAI
DOI: 10.4108/eai.18-10-2018.2287329
Abstract
Porous Coordination Polymers (PCPs) were synthesized using TCNQ and bipyridine anions that serve as connectors to form a 3-dimensional framework. In this study, zinc metal ions (Zn2+) and manganese (Mn2+) as the center of the complex compound coordination. XRD pattern of Zn (TCNQ-TCNQ) bpy.1.5Benzen 0T and 6T shows no difference, it suggest no magnetic field effect of 6T on the formation of crystal structure. The magnetic field exhibits effect on the morphology of the crystals. The SEM image shows that the 6T crystal surface smoother and the particle size larger than the 0T crystal for both complex compounds. The XRD pattern shows the stability properties of the structure for both types of these complex compounds and the SEM image also shows the stability properties of the compounds after the pretreatment process and after the adsorption process.
