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Advances of Science and Technology. 8th EAI International Conference, ICAST 2020, Bahir Dar, Ethiopia, October 2-4, 2020, Proceedings, Part II

Research Article

Graphitic Carbon Nitride with Extraordinary Photocatalytic Activity Under Visible Light Irradiation

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  • @INPROCEEDINGS{10.1007/978-3-030-80618-7_29,
        author={Gebrehiwot Gebreslassie and Pankaj Bharali and Gebremedhin Gebremariam and Assefa Sergawie and Esayas Alemayehu},
        title={Graphitic Carbon Nitride with Extraordinary Photocatalytic Activity Under Visible Light Irradiation},
        proceedings={Advances of Science and Technology. 8th EAI International Conference, ICAST 2020, Bahir Dar, Ethiopia, October 2-4, 2020, Proceedings, Part II},
        proceedings_a={ICAST PART 2},
        year={2021},
        month={7},
        keywords={Graphitic carbon nitride Porous materials Photodegradation},
        doi={10.1007/978-3-030-80618-7_29}
    }
    
  • Gebrehiwot Gebreslassie
    Pankaj Bharali
    Gebremedhin Gebremariam
    Assefa Sergawie
    Esayas Alemayehu
    Year: 2021
    Graphitic Carbon Nitride with Extraordinary Photocatalytic Activity Under Visible Light Irradiation
    ICAST PART 2
    Springer
    DOI: 10.1007/978-3-030-80618-7_29
Gebrehiwot Gebreslassie1,*, Pankaj Bharali2, Gebremedhin Gebremariam3, Assefa Sergawie1, Esayas Alemayehu4
  • 1: Department of Industrial Chemistry, College of Applied Sciences, Addis Ababa Science and Technology University
  • 2: Department of Chemical Sciences, Tezpur University, Napaam
  • 3: Department Chemistry, College of Natural and Computational Sciences, Mekelle University
  • 4: Faculty of Civil and Environmental Engineering, Jimma University
*Contact email: gebrehiwot.gebreslassie@aastu.edu.et

Abstract

Catalytic activities of graphitic carbon nitride (g-C3N4) are restricted thanks to inadequate visible light absorption and high rate electron–hole recombination. In this work, we synthesized porous g-C3N4using polycondensation process. Structural and physico-chemical characteristics of the prepared g-C3N4materials were studied via XRD, DRS, PL, FTIR, Raman spectroscopy, SEM, BET and CHN elemental analyzer. The prepared samples exhibited surprising catalytic activity for the photo-oxidation of rhodamine-B (RhB) in visible light irradiation. From the fabricated g-C3N4materials, the g-C3N4-550 showed photodegradation efficiency of 100% towards the RhB pollutant in water within 30 min. No appreciable decrease of the photocatalytic efficiency of g-C3N4was observed up to five consecutive cycles, confirming the synthesized g-C3N4was highly stable. Thus, this work gave a simple process for large scale production of highly visible light responsive and stable g-C3N4materials used for environmental remediation.

Keywords
Graphitic carbon nitride Porous materials Photodegradation
Published
2021-07-16
Appears in
SpringerLink
http://dx.doi.org/10.1007/978-3-030-80618-7_29
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